• Publications
  • Other Publications

180. Catalytic Enantioselective Nucleophilic α-Chlorination of Ketones with NaCl
Li, Z.; Wang, B.; Zhang, C.; Lo, W. Y.; Yang, L.; Sun, J.*
J. Am. Chem. Soc. 2024, 146, 2779-2788.

179. Mild Stereoselective Synthesis of Densely Substituted [3]Dendralenes via Ru-Catalyzed Intermolecular Dimerization of 1,1-Disubstituted Allenes
Li, S.; Feng, Q.; Song, L.;* Zhang, X.; Wu, Y.-D.;* Sun, J.*
J. Am. Chem. Soc. 2024, 146, 1532-1542.

178. Primary activation of para-quinone methides by chiral phosphoric acid for enantioselective construction of tetraarylmethanes
Han, Z.; Zhu, B.; Zang, Y.; Zhang, C.; Dong, X.-Q.; Huang, H.;* Sun, J.*
Chem. Sci. 2024, 15, 720-725.

175. Heterodifunctionalization of Electron-Rich Alkynes Catalyzed by in Situ Generated Silylium Ions
Su, X.; Wang, Y.; Feng, Q.; Sun, J.*
Org. Lett. 2024, 26, 421-426.

174. Organocatalytic Enantioselective Nucleophilic Addition of Indole Imine 5-Methides
Li, Y.; Huang, J.; Han, Z.; Huang, H.;* Hong, B.;* Sun, J.*
Org. Lett. 2024, 26, 396-400.

167. Asymmetric Synthesis of Remotely Chiral Naphthols and Naphthylamines via Naphthoquinone Methides
Liu, S.; Chan, K. L.; Lin, Z.;* Sun, J.*
J. Am. Chem. Soc. 2023, 145, 12802-12811.

166. Chiral Phosphoric Acid Catalyzed Redox Deracemization of Triarylmethanes
Liu, C.; Li, Z.; Li, P.;* Sun, J.*
Chem. Synth. 2023, 3, 22. (Invited submission)

148. Electricity-Driven Asymmetric Bromocyclization Enabled by Chiral Phosphate Anion Phase-Transfer Catalysis
Tan, X.;* Wang, Q.; Sun, J.*
Nat. Commun. 2023, 14, 357.

147. Ir-Catalyzed Regioselective Dihydroboration of Thioalkynes toward Gem-Diboryl Thioethers
Wang, Y.;1 Li, Y.;1 Wang, L.; Ding, S.; Song, L.;* Zhang, X.;* Wu, Y.-D.;* Sun, J.* (1: equal contribution)
J. Am. Chem. Soc. 2023, 145, 2305-2314.

146. Enantioselective Synthesis of Tetraarylmethanes through meta-Hydroxyl-directed Benzylic Substitution
Tan, X.;1 Deng, Z.;1 Wang, Q.; Chen, S.; Zhu, G.;* Sun, J.* (1: equal contribution)
Nat. Synth. 2023, 2, 275-285.

144. Catalytic Enantioselective Synthesis of 2,3'-Bis(indolyl)methanes Bearing All-Carbon Quaternary Stereocenters via 2-Indole Imine Methides
Han, Z.; Wang, W.; Zhuang, H.; Wang, J.; Wang, C.; Wang, J.;* Huang, H.;* Sun, J.*
Org. Lett. 2023, 25, 477-482.

142. Catalytic Asymmetric Synthesis of α-Tertiary Aminoketones from Sulfoxonium Ylides Bearing Two Aryl Groups
Zhou, Y.; Yue, X.; Jiang, F.; Sun, J.; Guo, W.*
Chem. Commun. 2023, 59, 1193-1196.

141. Visible-light-induced Organocatalytic Enantioselective N-H Insertion of α-Diazoesters Enabled by Indirect Free Carbene Capture
Guo, W.;* Zhou, Y.; Xie, H.; Yue, X.; Jiang, F.; Huang, H.; Han, Z.; Sun, J.*
Chem. Sci. 2023, 14, 843-848.

137. Nickel-Catalyzed Asymmetric Dicarbofunctionalization of Alkynes to Access Axially Chiral Styrenes
Tan, X.; Sun, J.*
Chem Catal. 2022, 2, 2813-2815. (Invited Preview article)

132. Organocatalytic Asymmetric Azidation of Sulfoxonium Ylides: Mild Synthesis of Enantioenriched α-Azido Ketones Bearing a Labile Tertiary Stereocenter
Guo, W.;* Jiang, F.; Li, S.; Sun, J.*
Chem. Sci. 2022, 13, 11648-11655.

129. Ru-Catalyzed Hydroboration of Ynones Leads to a Nontraditional Mode of Reactivity
Feng, Q.;1 Li, S.;1 Li, Z.; Yan, Q.; Lin, X.; Song, L.;* Zhang, X.;* Wu, Y.-D.;* Sun, J.* (1: equal contribution)
J. Am. Chem. Soc. 2022, 144, 14846-14855.

127. Ammonia to chiral α-amino acid
Yang, L.; Sun, J.*
Nat. Catal. 2022, 5, 471-472.
(Invited News and Views)

126. Quinone methides and indole imine methides as intermediates in enantioselective catalysis
Li, X.; Li, Z.; Sun, J.*
Nat. Synth. 2022, 1, 426-438.
(Invited review article)

125. Ruthenium-Catalyzed Geminal Hydroborative Cyclization of Enynes
Tan, Y.-X.; Li, S.; Song, L.;* Zhang, X.; Wu, Y.-D.;* Sun, J.*
Angew. Chem., Int. Ed. 2022, 61, e202204319.

123. Catalytic Asymmetric Allylic Substitution/Isomerization with Central Chirality Transposition
Han, Z.; Zhuang, H.; Tang, L.; Zang, Y.; Guo, W.; Huang, H.;* Sun, J.*
Org. Lett. 2022, 24, 4246-4251.

122. Enantioselective synthesis of triarylmethanes via organocatalytic transfer hydrogenation of para-quinone methides
Han, Z.; Zang, Y.; Liu, C.; Guo, W.; Huang, H.;* Sun, J.*
Chem. Commun. 2022, 58, 7128-7131.

121. Reductive Opening of Oxetanes Catalyzed by Frustrated Lewis Pairs: Unexpected Aryl Migration via Neighboring Group Participation
Tang, L.; Zang, Y.; Guo, W.; Han, Z.; Huang, H.;* Sun, J.*
Org. Lett. 2022, 24, 3259-3264.

119. Organocatalytic discrimination of non-directing aryl and heteroaryl groups: enantioselective synthesis of bioactive indole-containing triarylmethanes
Yan, Q.;1 Duan, M.;1 Chen, C.; Deng, Z.; Wu, M.; Yu, P.; He, M.-L.;* Zhu, G.;* Houk, K. N.;* Sun, J.*
Chem. Sci. 2022, 13, 5767-5773.
(1: equal contribution)

117. Asymmetric Synthesis of Pyrrolidines via Oxetane Desymmetrization
Zhang, R.;1 Sun, M.;1 Yan, Q.;1 Lin, X.; Li, X.; Fang, X.; Sung, H. H. Y.; Williams, I. D.; Sun, J.*
Org. Lett. 2022, 24, 2359-2364.
(1: equal contribution)

114. Catalytic Enantioselective Synthesis of 2,3-Dihydrobenzo[b]oxepines via Asymmetric Oxetane Opening by Internal Carbon Nucleophiles
Zhang, T.; Zhuang, H.; Tang, L.; Han, Z.; Guo, W.; Huang, H.;* Sun, J.*
Org. Lett. 2022, 24, 207-212.

113. Asymmetric dearomatization enabled by chiral Bronsted acid activation of ynamides
Li, X.; Sun, J.*
Sci. Chin. Chem. 2022, 65, 3-4.
(Invited Highlight)

111. SPHENOL, A New Chiral Framework for Asymmetric Synthesis
Zhang, R.;1 Ge, S.;1 Sun, J.*
J. Am. Chem. Soc. 2021, 143, 12445-12449.
(1: equal contribution)

110. Mild Intermolecular Synthesis of a Cyclopropane-Containing Tricyclic Skeleton: Unusual Reactivity of Isobenzopyryliums
Liu, S.; Qian, H.; Zhang, T.; Xie, H.; Han, Z.; Guo, W.; Huang, H.;* Sun, J.*
Angew. Chem., Int. Ed. 2021, 60, 21272-21276.

109. Organocatalytic Asymmetric Formal Oxidative Coupling for the Construction of All-Aryl Quaternary Stereocenters
Li, Z.; Li, Y.; Li, X.; Wu, M.; He, M.-L.;* Sun, J.*
Chem. Sci. 2021, 12, 11793-11798.

108. Organocatalytic Enantioselective Dearomatization of Thiophenes by 1,10-Conjugate Addition of Indole Imine Methides
Li, X.; Duan, M.; Yu, P.; Houk, K. N.;* Sun, J.*
Nat. Commun. 2021, 12, 4881.

107. Organocatalytic Asymmetric Synthesis of α-Amino Esters from Sulfoxonium Ylides
Guo, W.; Wang, M.; Han, Z.; Huang, H.;* Sun, J.*
Chem. Sci. 2021, 12, 11191-11196.

106. An Unusual Formal Migrative Cycloaddition of Aurone-derived Azadienes: Synthesis of Benzofuran-fused Nitrogen Heterocycles
Feng, Q.; Wu, A.; Zhang, X.; Song, L.;* Sun, J.*
Chem. Sci. 2021, 12, 7953-7957.

104. Ru-Catalyzed [3 + 2] Cycloaddition of Nitrile Oxides and Electron-Rich Alkynes with Reversed Regioselectivity
Feng, Q.; Huang, H.; Sun, J.*
Org. Lett. 2021, 23, 2431-2436.

103. An Organocatalytic Kinetic Resolution of Aziridines by Thiol Nucleophiles
Sun, S.; Wang, Z.; Li, S.; Zhou, C.; Song, L.; Huang, H.;* Sun, J.*
Org. Lett. 2021, 23, 554-558.

102. Catalytic Enantioselective Synthesis of Spirooxindoles by Oxidative Rearrangement of Indoles
Qian, C.; Li, P.;* Sun, J.*
Angew. Chem., Int. Ed. 2021, 60, 5871-5875.

101. Mild C-C Bond Formation via Lewis Acid Catalyzed Oxetane Ring Opening with Soft Carbon Nucleophiles
Huang, H.; Zhang, T.; Sun, J.*
Angew. Chem., Int. Ed. 2021, 60, 2668-2673.

100. In(OTf)3-Catalyzed Synthesis of 2,3-Dihydro-1H-benzo[e]indoles and 2,3-Dihydrobenzofurans via [3 + 2] Annulation
Liu, S.; Zang, Y.; Huang, H.;* Sun, J.*
Org. Lett. 2020, 22, 8219-8223.

99. Catalytic Enantioselective Synthesis of Chiral Tetraarylmethanes
Li, X.; Duan, M.; Deng, Z.; Shao, Q.; Chen, M.; Zhu, G.;* Houk, K. N.;* Sun, J.*

Nat. Catal. 2020, 3, 1010-1019.

98. 3-Aminooxetanes: Versatile 1,3-Amphoteric Molecules for Intermolecular Annulation Reactions
Lai, Z.; Zhang, R.; Feng, Q.; Sun, J.*
Chem. Sci. 2020, 11, 9945-9949.

97. Synthesis of Coumarins via [4+2] Cyclization of Siloxy Alkynes and Salicylaldehydes
Qian, H.; Sun, J.*
Synlett 2020, 32, 207-210. (Invited contribution to the cluster issue of heterocycles)

96. An Efficient [3+2] Annulation for the Asymmetric Synthesis of Densely-Functionalized Pyrrolidinones and γ-Butenolides
Qian, H.; Sun, S.; Zhao, W.; Sun, J.*
Chem. Commun. 2020, 56, 11295-11298.

95. Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of α-Tertiary Amino Ketones from Sulfonium Ylides
Guo, W.; Luo, Z.; Sung, H. H. Y.; Williams, I. D.; Li, P.;* Sun, J.*
J. Am. Chem. Soc. 2020, 142, 14384-14390.

94. Ru-Catalyzed Geminal Hydroboration of Silyl Alkynes via a New gem-Addition Mechanism
Feng, Q.; Wu, H.-N.; Li, X.; Song, L.; Chung, L. W.;*; Wu, Y.-D.;* Sun, J.*
J. Am. Chem. Soc. 2020, 142, 13867-13877.

93. Organocatalytic Enantioselective Synthesis of Chiral Allenes: Remote Asymmetric 1,8-Addition of Indole Imine Methides
Li, X.; Sun, J.*
Angew. Chem., Int. Ed. 2020, 59, 17049-17054.

92. Benzannulation of Isobenzopyryliums with Electron-Rich Alkynes: A Modular Access to β-Functionalized Naphthalenes
Wu, A.; Qian, H.; Zhao, W.; Sun, J.*
Chem. Sci. 2020, 11, 7957-7962.

91. A Study of the Reactivity of (Aza-)Quinone Methides in Selective C6-Alkylations of Indoles
Yan, J.; Zhang, Z.; Chen, M.; Lin, Z.;* Sun, J.*
ChemCatChem 2020, 12, 5053-5057. (Invited contribution to a Special Collection on "Phosphorus in Catalysis")

90. Unusual Skeletal Reorganization of Oxetanes for the Synthesis of 1,2-Dihydroquinolines
Wang, G.; Huang, H.; Guo, W.; Qian, C.; Sun, J.*
Angew. Chem., Int. Ed. 2020, 59, 11245-11249.

89. Synthesis of medium-sized lactones from siloxy alkynes via ring expansion
Wu, A.; Zhao, W.; Sun, J.*
Tetrahedron 2020, 76, 131163.
(Invited contribution)

88. HNTf2-Catalyzed Synthesis of Hydrodibenzofurans by an Epoxidation/Semipinacol Rearrangement Cascade
Wong, T. H. M.; Li, X.; Ma, D.; Sun, J.*
Org. Lett. 2020, 22, 1951-1954.

87. Catalytic Enantioselective Synthesis of 1,4-Benzodioxepines
Zhou, X.; Sun, G.; Huang, H.; Wang, J.*; Yang, W.*; Sun, J.*
Org. Lett. 2020, 22, 249-252.

86. Ru-Catalyzed Migratory Geminal Semi-Hydrogenation of Internal Alkynes to Terminal Olefins
Song, L.; Feng, Q.; Wang, Y.; Ding, S.; Wu, Y.-D.; Zhang, X.; Chuang, L. W.;* Sun, J.*
J. Am. Chem. Soc. 2019, 141, 17441-17451.

85. Asymmetric Desymmetrization of Oxetanes for the Synthesis of Chiral Tetrahydrothiophenes and Tetrahydroselenophenes
Zhang, R.; Guo, W.; Duan, M.; Houk, K. N.;* Sun, J.*
Angew. Chem., Int. Ed. 2019, 58, 18055-18060.

84. Organocatalytic Enantioconvergent Synthesis of Tetrasubstituted Allenes via Asymmetric 1,8-Addition to aza-para-Quinone Methides
Chen, M.; Qian, D.; Sun, J.*
Org. Lett. 2019, 21, 8127-8131.

83. Catalytic Enantioselective House-Meinwald Rearrangement: Efficient Construction of All-Carbon Quaternary Stereocenters
Ma, D.; Miao, C.-B.; Sun, J.*
J. Am. Chem. Soc. 2019, 141, 13783-13787.

82. Organocatalytic Enantioselective Functionalization of Unactivated Indole C(sp3)-H Bonds
Ma, D.; Zhang, Z.; Chen, M.; Lin, Z.;* Sun, J.*
Angew. Chem., Int. Ed. 2019, 58, 15916-15921.

81. A Mild Catalytic Synthesis of 2-Oxazolines via Oxetane Ring-Opening: Rapid Access to A Diverse Family of Natural Products
Huang, H.; Yang, W.; Chen, Z.; Lai, Z.; Sun, J.*
Chem. Sci. 2019, 10, 9586-9590.

80. Electrochemical Synthesis of β-Hydroxy-, β-Alkoxy-, and β-Carbonyloxy Sulfones by Vicinal Difunctionalization of Olefins
Zhang, Z.; Yan, J.; Ma, D.; Sun, J.*
Chin. Chem. Lett. 2019, 30, 1509-1511.
(Invited contribution)

79. Synthesis of Eight-Membered Lactams via Formal [6+2] Cyclization of Siloxy Alkynes and Vinylazetidines
Wu, A.; Feng, Q.; Sung, H. H. Y.; Williams, I. D.;* Sun, J.*
Angew. Chem., Int. Ed. 2019, 58, 6776-6780.

78. A [3+2] Cyclization of Siloxyalkynes and Isocyanides for the Syn- thesis of Oxazoles
Wu, A.; Sun, J.*
Synlett 2019, 30, 515-518.
(Invited contribution to the 30 Years SYNLETT - Pearl Anniversary Issue)

77. Recent Progress in Asymmetric Ion-Pairing Catalysis on Ammoniums
Qian, D.;* Sun, J.*
Chem. Eur. J. 2018, 25, 3740-3751.
(Invited submission)

76. Triflimide (HNTf2) in Organic Synthesis
Zhao, W.; Sun, J.*
Chem. Rev. 2018, 118, 10349-10392.

75. NHC-Catalyzed Electrophilic Trifluoromethylation: Efficient Synthesis of γ-Trifluoromethyl α,β-Unsaturated Esters
Yang, W.;1 Ma, D.;1 Zhou, Y.; Dong, X.; Lin, Z.;* Sun, J.*
Angew. Chem., Int. Ed. 2018, 57, 12097-12101.
(1: equal contribution)

74. Stereoselective Synthesis of Fully-Substituted Acrylonitriles via Formal Acylcyanation of Electron-Rich Alkynes
Liu, B.;1 Wang, Y.;1 Chen, Y.; Wu, Q.; Zhao J.;* Sun, J.*
Org. Lett. 2018, 20, 3465-3468.
(1: equal contribution)

72. An Organocatalytic Asymmetric Synthesis of Chiral β,β-Diaryl-α-amino Acids via Addition of Azlactones to In-Situ Generated para-Quinone Methides
Yan, J.;1 Chen, M.;1 Sung, H. H.-Y.; Williams, I. D; Sun, J.* (1: equal contribution)
Chem. Asian J. 2018, 13, 2440-2444.
(Invited submission)

71. Organocatalytic Enantioselective Synthesis of Chiral Diarylmethylamines from Racemic Alcohols
Chen, M.; Han, Y.; Ma, D.; Wang, Y.; Lai, Z.; Sun, J.*
Chin. J. Chem. 2018, 36, 519-525.
(Invited submission)

70. Counterion-Induced Asymmetric Control on Azetidiniums: A Facile Access to Chiral Amines
Qian, D.;1 Chen, M.;1 Bissember, A. C.; Sun, J.*
(1: equal contribution)
Angew. Chem., Int. Ed. 2018, 57, 3763-3766.

69. Organocatalytic Synthesis of Chiral Tetrasubstituted Allenes from Racemic Propargylic Alcohols
Qian, D.; Wu, L.; Lin, Z.;* Sun, J.*
Nature Commun. 2017, 8, 567.

68. How Understanding the Role of an Additive Can Lead to an Improved Synthetic Protocol without an Additive: Organocatalytic Synthesis of Chiral Diarylmethyl Alkynes
Chen, M.; Sun, J.*
Angew. Chem., Int. Ed. 2017, 56, 11966-11970.

67. Catalytic Asymmetric N-Alkylation of Indoles and Carbazoles via 1,6-Conjugate Addition of Aza-para-Quinone Methides
Chen, M.; Sun, J.*
Angew. Chem., Int. Ed. 2017, 56, 4583-4587.

66. Enantioselective [4 + 2] Cycloaddition of o-Quinone Methides and Vinyl Sulfides: Indirect Access to Generally Substituted Chiral Chromanes
Wang, Z.; Sun, J.*
Org. Lett. 2017, 19, 2334-2337.

65. N-Heterocyclic Carbene Catalyzed γ-Dihalomethylenation of Enals via Single Electron Transfer
Yang, W.; Hu, W.; Dong, X.; Li, X.; Sun, J.*
Angew. Chem., Int. Ed. 2016, 55, 15783-15786.

64. Catalytic Enantioselective Aza-Piancatelli Rearrangement
Li, H.; Tong, R.; Sun, J.*
Angew. Chem., Int. Ed. 2016, 55, 15125-15128.

63. Metal-Free [2+2+2] Cycloaddition of Ynamides and Nitriles: Mild and Regioselective Synthesis of Fully Substituted Pyridines
Wang, Y.; Song, L.-J.; Zhang, X.;* Sun, J.*
Angew. Chem., Int. Ed. 2016, 55, 9704-9708.

62. Ir-Catalyzed Regio- and Stereoselective Hydrosilylation of Internal Thioalkynes: A Combined Experimental and Computational Study
Song, L.-J.; Ding, S.; Wang, Y.; Zhang, X.;* Wu, Y.-D.;* Sun, J.*
J. Org. Chem. 2016, 81, 6157-6164.

61. Enantioselective Chloride Opening of Oxetanes: Unusual Use of Wet Molecular Sieves for Controlled Release of HCl
Yang, W.; Wang, Z.; Sun, J.*
Angew. Chem., Int. Ed. 2016, 55, 6954-6958.

60. Organocatalytic Enantioselective Desymmetrization of meso-Aziridines and Prochiral Azetidines
Wang, Z.; Hong, W.-X.; Sun, J.*
Curr. Org. Chem. 2016, 20, 1851-1861. (Invited review)

59. Chiral Phosphoric Acid Catalyzed Asymmetric Addition of Naphthols to para-Quinone Methides
Wong, Y. F.; Wang, Z.; Sun, J.*
Org. Biomol. Chem. 2016, 14, 5751-5754.
(Invited contribution to the "New Talent" issue)

58. A One-Pot Oxidation/Cycloaddition Cascade Synthesis of 2,4-Diaryl Chromans via ortho-Qunione Methides
Wong, Y. F.; Wang, Z.; Hong, W.-X.; Sun, J.*
Tetrahedron 2016, 72, 2748-2751.
(Invited contribution to the issue on Catalytic C-C Bond Formation by C-H Functionalization and C-C Bond Cleavage)

57. Organocatalytic Enantioselective Synthesis of 1,4-Dioxanes and Other Oxa-Heterocycles by Oxetane Desymmetrization
Yang, W.; Sun, J.*
Angew. Chem., Int. Ed. 2016, 55, 1868-1871.

56. Enantioselective Addition of Thiols to ortho-Quinone Methides Catalyzed by Chiral Phosphoric Acids
Lai, Z.; Sun, J.*
Synlett 2016, 27, 555-558.
(Invited contribution to the Chiral Phosphoric Acid cluster issue)

55. Organocatalytic Asymmetric Nucleophilic Addition to ortho-Quinone Methides by Alcohols
Lai, Z.; Wang, Z.; Sun, J.*
Org. Lett. 2015, 17, 6058-6061.

54. Recent Advances in Catalytic Asymmetric Reactions of ortho-Quinone Methides
Wang, Z.; Sun, J.*
Synthesis 2015, 47, 3629-3644. (Invited review)

53. Catalytic Asymmetric 1,6-Conjugate Addition of para-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters
Wang, Z.; Wong, Y. F.; Sun, J.*
Angew. Chem., Int. Ed. 2015, 54, 13711-13714.

52. Triflimide (Update)
Sun, J.
e-Encyclopedia of Reagents for Organic Synthesis, 2015.
 

51. Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium Ring Lactams
Zhao, W. 1; Qian, H. 1; Li, Z.*; Sun, J.* (1: equal contribution)

Angew. Chem., Int. Ed. 2015, 54, 10005-10008.

50. Catalytic Enantioselective Intermolecular Desymmetrization of Azetidines
Wang, Z.; Sheong, F. K.; Sung, H. H. Y.; Williams, I. D.; Lin, Z.*; Sun, J.*
J. Am. Chem. Soc. 2015, 137, 5895-5898.
 

49. Highly Regio- and Stereoselective Hydrosilylation of Internal Thioalkynes Under Mild Conditions
Ding, S.; Song, L.-J.; Wang, Y.; Zhang, X.*; Chung, L. W.*; Wu, Y.-D.*; Sun, J.*
Angew. Chem., Int. Ed. 2015, 54, 5632-5635.
 

48. Organocatalytic Enantio- and Diastereoselective Synthesis of 1,2-Dihydronaphthalenes from Isobenzopyrylium Ions
Qian, H.; Zhao, W.; Wang, Z.; Sun, J.*
J. Am. Chem. Soc. 2015, 137, 560-563.
 

47. Organocatalytic Asymmetric Synthesis of 1,1-Diarylethanes by Transfer Hydrogenation
Wang, Z.; Ai, F.; Wang, Z.; Zhao, W.; Zhu, G.*; Lin, Z.*; Sun, J.*
J. Am. Chem. Soc. 2015, 137, 383-389.
 

46. Enantioselective Formation of All-Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group
Zhao, W.; Wang, Z.; Chu, B.; Sun, J.*
Angew. Chem., Int. Ed. 2015, 54,
1910-1913.
 

45. N-Heterocyclic Carbene Catalyzed Enantioselective α-Fluorination of Aliphatic Aldehydes and α-Chloro Aldehydes: Synthesis of α-Fluoro Esters, Amides, and Thioesters
Dong, X.; Yang, W.; Hu, W.; Sun, J.*
Angew. Chem., Int. Ed. 2015, 54, 660-663.
 

44. Dithieno[3,2-b:2',3'-d]pyran-Containing Organic D-p-A Sensitizers for Dye-Sensitized Solar Cells
Chu, B.; Wang, H.; Xerri, B.; Lee, K-H.; Yang, T.; Wang, Z.; Lin, Z.; Liang, Y.*; Adamo, C.*; Yang, S.*; Sun, J.*
RSC Adv. 2014, 4, 62472-62475.
 

42. Siloxy Alkynes in Annulation Reactions
Qian, H.; Zhao, W.; Sun, J.*
Chem. Rec. 2014, 14, 1070-1085. (Invited Account)
 

41. Catalytic Asymmetric Nucleophilic Openings of 3-Substituted Oxetanes
Wang, Z.; Chen, Z.; Sun, J.*
Org. Biomol. Chem. 2014, 12, 6028-6032. (Invited Perspective)
 

40. Catalytic Asymmetric α-Aldol Reaction of Vinylogous N-Heterocyclic Carbene Enolates: Formation of Quaternary and Labile Tertiary Stereocenters
Dong, X.; Sun, J.*
Org. Lett. 2014, 16, 2450-2453.
 

39. Organocatalytic Enantio- and Diastereoselective Assembly of Thiazolidine Scaffolds by Formal [3+2] Annulation
Qian, H.; Sun, J.*
Asian J. Org. Chem. 2014, 3, 387-390. (Invited contribution for the speical issue of Organocatalysis)
 

38. Ir-Catalyzed Intermolecular Azide-Alkyne Cycloaddition of Internal Thioalkynes under Mild Conditions
Ding, S.; Jia, G.*; Sun, J.*
Angew. Chem., Int. Ed. 2014, 53, 1877
-1880.
 

37. New Strategies for Medium and Large Ring Lactone Synthesis
Zhao, W.; Sun, J.*
Synlett. 2014, 25, 303-307. (Invited SYNPACTS highlight)
 

36. Multi-Targeted Organometallic Ruthenium(II)-Arene Anticancer Complexes Bearing Inhibitors of Poly(ADP-Ribose) Polymerase-1: A Strategy to Improve Cytotoxicity
Wang, Z.; Qian, H.; Yiu, S.-M.; Sun, J.; Zhu, G.*
J. Inorg. Biochem. 2014, 131, 47-55.
 

34. Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes
Qian, H.; Yu, X.; Zhang, J.*; Sun, J.*
J. Am. Chem. Soc. 2013, 135, 18020-18023.
 

33. Enantio- and Diastereoselective Assembly of Tetrahydrofuran and Tetrahydropyran Skeletons with All-Carbon Quaternary Stereocenters
Chen, Z.; Sun, J.*
Angew. Chem., Int. Ed. 2013, 52, 13593-13596.
 

32. Chiral Phosphoric Acid Catalyzed Enantioselective Desymmetrization of meso-Epoxides by Thiols
Wang, Z.; Law, W. K.; Sun, J.*
Org. Lett. 2013, 15, 5964-5966.
 

31. Ligand-Controlled Remarkable Regio- and Stereodivergence in Intermolecular Hydrosilylation of Internal Alkynes: Experimental and Theoretical Studies
Ding, S.; Song, L.-J.; Chung, L. W.; Zhang, X.; Sun, J.*; Wu, Y.-D.*
J. Am. Chem. Soc. 2013, 135, 13835-13842.
 

30. N-Heterocyclic Carbene (NHC) Catalyzed Synthesis of α,α-Difluoro Esters
Dong, X.; Zhao, Y.-M.; Sun, J.*
Synlett 2013, 24, 1221-1224. (Invited contribution for the Cluster on N-Heterocyclic Carbene Catalysis)
 

29. Catalytic Enantioselective Assembly of Tetrahydroisoquinolines and Their Analogues Bearing A C-4 Stereocenter: A Formal Synthesis of (+)-(8S,13R)-Cyclocelabenzine
Chen, Z.1; Wang, Z.1; Sun, J.* (1: equal contribution)
Chem. Eur. J. 2013, 19, 8426-8430.
 

28. Catalytic Enantioselective Intermolecular Desymmetrization of 3-Substituted Oxetanes
Wang, Z.; Chen, Z.; Sun, J.*
Angew. Chem., Int. Ed. 2013, 52, 6685-6688. (front cover)
 

27. A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow Addition
Zhao, W.; Li, Z.*; Sun, J.*
J. Am. Chem. Soc. 2013, 135, 4680-4683
 

26. Stereoselective Synthesis of Aminoindanols via An Efficient Cascade aza-Michael/Aldol Reaction
Qian, H.; Zhao, W.; Sung, H. H.-Y.; Williams, I. D.; Sun, J.*
Chem. Commun. 2013, 49, 4361-4363.
(Invited contribution for the Emerging Investigators 2013 issue)
 

25. Complex Bioactive Alkaloid-Type Polycycles through Efficient Catalytic Asymmetric Multicomponent Aza-Diels-Alder Reaction of Indoles with Oxetane as Directing Group
Chen, Z.; Wang, B.; Wang, Z.; Zhu, G.*; Sun, J.*
Angew. Chem., Int. Ed. 2013, 52, 2027-2031.
 

24. Enantioselective Synthesis of β,γ-Unsaturated α-Fluoroesters Catalyzed by N-Heterocyclic Carbenes
Zhao, Y.-M.; Cheung, M. S.; Lin, Z.*; Sun, J.*
Angew. Chem., Int. Ed. 2012, 51, 10359-10363.
 

23. Synthesis of 8-Membered Lactones via Intermolecular [6+2] Cyclization of New Amphoteric Molecules with Siloxy Alkynes
Zhao, W.; Wang, Z.; Sun, J.*
Angew. Chem., Int. Ed. 2012, 51, 6209-6213.
 

22. NHC-Catalyzed Intramolecular Redox Reaction of Alkynals: An Efficient Synthesis of Allenoates
Zhao, Y.; Tam, Y.; Wang, Y.; Li, Z.; Sun, J.*
Org. Lett. 2012, 14, 1398-1401.
 

19. Triflimide (review)
Sun, J.*
e-Encyclopedia of Reagents for Organic Synthesis, 2010.